ADP-7

TECHNICAL PRODUCT BULLETIN #SW-68
USEPA, OEM REGULATIONS IMPLEMENTATION DIVISION
ORIGINAL LISTING DATE: AUGUST 22, 2016
“ADP-7”
LAST COMMUNICATION WITH MANUFACTURER: 12/23/2019
LAST ATTEMPT: 7/15/2021

I. NAME, BRAND, OR TRADEMARK
ADP-7 Type of Product: Surface Washing Agent

II. NAME, ADDRESS, AND TELEPHONE NUMBER OF MANUFACTURER/CONTACT
Petro-Green, Inc. 3952 Candlenut Lane Dallas, TX 75244 Phone: updated information required Email: [email protected] Website: https://petro-green.com/ (Mr. Michael Paddock)	Mailing Address Petro-Green, Inc. P.O. Box 814665 Dallas, TX 75381 (Mr. Michael Paddock)

III. NAME, ADDRESS, AND TELEPHONE NUMBER OF PRIMARY DISTRIBUTORS
Petro-Green, Inc. 3952 Candlenut Lane Dallas, TX 75244 Phone: updated information required Email: [email protected] Website: https://petro-green.com/ (Mr. Michael Paddock)	Mailing Address Petro-Green, Inc. P.O. Box 814665 Dallas, TX 75381 (Mr. Michael Paddock)

IV. SPECIAL HANDLING AND WORKER PRECAUTIONS FOR STORAGE AND FIELD APPLICATION
1. Flammability: Non-Flammable (DOT: Non-Hazardous) 2. Ventilation: In most instances there will be no special requirements. However, if exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive pressure supplied air respirators may be required for high airborne contaminant concentrations. 3. Skin and eye contact; protective clothing; treatment in case of contact: First Aid: Skin/Body Contact – Wash off immediately with soap and water while removing all contaminated clothing and shoes. Wash all before reuse. Consult physician if irritation persists. Eyes – Immediately flush with plenty of water. After initial flushing, remove contact lenses if present and continue flushing for at least 15 minutes. If symptoms persist contact physician. Ingestion – Rinse mouth. Drink plenty of water. Do NOT induce vomiting. If symptoms persist contact physician. Inhalation – Move to fresh air. If breathing is irregular or stopped administer artificial respiration. Call physician. 4.a. Maximum storage temperature: 120°F continuous, 140°F up to 5 days 4.b. Minimum storage temperature: 26°F 4.c. Optimum storage temperature range: 40°F to 110°F 4.d. Temperatures of phase separations and chemical changes: Stable within storage temperature range.

IV. SPECIAL HANDLING AND WORKER PRECAUTIONS FOR STORAGE AND FIELD APPLICATION

1. Flammability: Non-Flammable (DOT: Non-Hazardous)
2. Ventilation: In most instances there will be no special requirements. However, if exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive pressure supplied air respirators may be required for high airborne contaminant concentrations.
3. Skin and eye contact; protective clothing; treatment in case of contact: First Aid: Skin/Body Contact – Wash off immediately with soap and water while removing all contaminated clothing and shoes. Wash all before reuse. Consult physician if irritation persists. Eyes – Immediately flush with plenty of water. After initial flushing, remove contact lenses if present and continue flushing for at least 15 minutes. If symptoms persist contact physician. Ingestion – Rinse mouth. Drink plenty of water. Do NOT induce vomiting. If symptoms persist contact physician. Inhalation – Move to fresh air. If breathing is irregular or stopped administer artificial respiration. Call physician.
4.a. Maximum storage temperature: 120°F continuous, 140°F up to 5 days
4.b. Minimum storage temperature: 26°F
4.c. Optimum storage temperature range: 40°F to 110°F
4.d. Temperatures of phase separations and chemical changes: Stable within storage temperature range.

V. SHELF LIFE
Unlimited in sealed poly drums (as delivered).

VI. RECOMMENDED APPLICATION PROCEDURE
1. Application Method: For spills on soils, sandy or rocky areas: ADP-7 can be pre-mixed into water, or educed into a water flow, to be sprayed directly onto the oil spill. 2. Concentration/Application Rate: For spills on land: Typical dilution is one gallon of ADP-7 diluted with 42 gallons of water (approximately 2.4% concentration). Higher water temperatures (over 78°F) and/or good agitation during application will allow you to reduce the concentration strength. Aged or asphaltic spills may be more resistant to removal. Heating the solution to 150°F in a hot water washing rig, or a common oil field “hot oiler” truck will increase effectiveness. 3. Conditions for Use: ADP-7 is effective in salt water or fresh water, with no limitations as to usage within optimum temperature parameters (application may be made at or above 35°F, with optimum above 48°F). A sorbent boom or other containment equipment should be positioned prior to product application and should remain in place during product use to collect runoff from application and removal operations. The oil/product residue should be collected and removed from the site. Collection process should be determined by onsite coordinator based on practices of the area. Residue should be disposed of according to local, state and federal regulations.

VI. RECOMMENDED APPLICATION PROCEDURE

1. Application Method: For spills on soils, sandy or rocky areas: ADP-7 can be pre-mixed into water, or educed into a water flow, to be sprayed directly onto the oil spill.
2. Concentration/Application Rate: For spills on land: Typical dilution is one gallon of ADP-7 diluted with 42 gallons of water (approximately 2.4% concentration). Higher water temperatures (over 78°F) and/or good agitation during application will allow you to reduce the concentration strength. Aged or asphaltic spills may be more resistant to removal. Heating the solution to 150°F in a hot water washing rig, or a common oil field “hot oiler” truck will increase effectiveness.
3. Conditions for Use: ADP-7 is effective in salt water or fresh water, with no limitations as to usage within optimum temperature parameters (application may be made at or above 35°F, with optimum above 48°F). A sorbent boom or other containment equipment should be positioned prior to product application and should remain in place during product use to collect runoff from application and removal operations. The oil/product residue should be collected and removed from the site. Collection process should be determined by onsite coordinator based on practices of the area. Residue should be disposed of according to local, state and federal regulations.

VII.TOXICITY AND EFFECTIVENESS

a. Toxicity:

Material Tested	Species	LC50 (ppm)
ADP-7	Menidia beryllina	20.28 96-hr
	Mysidopsis bahia	22.36 48-hr
No. 2 Fuel Oil	Menidia beryllina	17.46 96-hr
	Mysidopsis bahia	5.30 48-hr
ADP-7 &	Menidia beryllina	14.10 96-hr
No. 2 Fuel Oil (1:10)	Mysidopsis bahia	3.24 48-hr
Reference Toxicant (SDS)	Menidia beryllina	3.42 96-hr
	Mysidopsis bahia	7.81 48-hr

b. Effectiveness: NA

VIII. MICROBIOLOGICAL ANALYSIS
NA

IX. PHYSICAL PROPERTIES
1. Flash Point (ASTM D-56): >212°F 2. Pour Point (ASTM D-97): 21ºF 3. Viscosity (ASTM D-445): 81.4 cst @ 40°C 4. Specific Gravity (ASTM D-287): 1.0985 at 60°F 5. pH (ASTM D-1293): 9.9 6. Surface Active Agents: Anionic and nonionic 7. Solvents: Confidential 8. Additives: Confidential 9. Solubility: Miscible in oil, water, and solvents

X. ANALYSIS FOR HEAVY METALS, CYANIDE, AND CHLORINATED HYDROCARBONS

Compound	Concentration (ppm)
Arsenic	<0.485
Cadmium	<0.243
Chromium	<0.243
Copper	<0.485
Lead	<0.585
Mercury	<3.26 µg/L
Nickel	<0.485
Zinc	<0.485
Cyanide	<0.115
Chlorinated Hydrocarbons	<2.00

ADP-7

Emergency Response